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Title:The Design of Cyanometallate Cages for Alkali Ion Separation
Author(s):Kuhlman, Matthew Lee
Doctoral Committee Chair(s):Rauchfuss, Thomas B.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:The metal sulfide cluster, [(cymene)2Ru3S 2(NCMe)3]2+, reacts with various equivalents of sulfide to give rise to cluster-of-clusters i.e. [(cymene)4Ru 5S4]2+ and [(cymene)6Ru9S 8]2+. The new valence isomer of the [(cymene)4Ru 4S3]2+ was characterized and shown to convert to the black Roussin motif. Finally, this work also demonstrates the potential utility of Ru-S clusters as catalysts for hydrogen production.
Issue Date:2004
Type:Text
Language:English
Description:222 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2004.
URI:http://hdl.handle.net/2142/84168
Other Identifier(s):(MiAaPQ)AAI3160908
Date Available in IDEALS:2015-09-25
Date Deposited:2004


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