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Title:Development of a Highly Active Molybdenum Catalyst for Alkyne Metathesis and Its Application in Polymer and Macrocycle Synthesis
Author(s):Zhang, Wei
Doctoral Committee Chair(s):Moore, Jeffrey S.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Calculations on thermodynamic stabilities of several shape-persistent macrocycles indicated that the high yields of those macrocycles are due to their own stabilities, which serve as the driving force for their amplification under reversible metathesis conditions. These successful cases demonstrate the great importance of energy gap principle in design and synthesis of shape-persistent macrocycles.
Issue Date:2005
Type:Text
Language:English
Description:239 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2005.
URI:http://hdl.handle.net/2142/84207
Other Identifier(s):(MiAaPQ)AAI3199196
Date Available in IDEALS:2015-09-25
Date Deposited:2005


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