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Title:Studies on the Silanol-Based Cross-Coupling Reaction: (1) Development of Methods for the Synthesis of Aryl and Heteroaryldimethysilanols, (2) Expansion of the Substrate Scope of the Cross-Coupling Reaction and (3) Investigations on the Transmetalation of Organosilanols to Transition Metals
Author(s):Kallemeyn, Jeffrey M.
Doctoral Committee Chair(s):Denmark, Scott E.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:To further illuminate the mechanism of transmetalation of alkenyldimethylsilanols a number of molecular traps have been designed, synthesized and subjected to the cross-coupling reaction. A clear preference for formation of the cross-coupling products was observed in these investigations.
Issue Date:2007
Type:Text
Language:English
Description:359 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007.
URI:http://hdl.handle.net/2142/84259
Other Identifier(s):(MiAaPQ)AAI3269934
Date Available in IDEALS:2015-09-25
Date Deposited:2007


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