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Title:Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols: I. New Methods That Employ Alkynylsilanols and Bissilyl Reagents. II. Mechanistic Analysis of the Cross-Coupling of Aryldimethylsilanolates
Author(s):Tymonko, Steven
Doctoral Committee Chair(s):Denmark, Scott E.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Mechanistic investigations of the palladium-catalyzed cross-coupling of aryldimethylsilanolates demonstrated that transmetalation proceeds directly from an arylpalladium(II) silanolate intermediate without external activation. Arylpalladium(II) silanolate complexes bearing phosphine ligands were isolated and characterized. These complexes produce biaryl products via ligand dissociation and transmetalation.
Issue Date:2007
Type:Text
Language:English
Description:587 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007.
URI:http://hdl.handle.net/2142/84283
Other Identifier(s):(MiAaPQ)AAI3290408
Date Available in IDEALS:2015-09-25
Date Deposited:2007


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