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Title:Palladium-Catalyzed Cross-Coupling Reactions of Heteroaryldimethylsilanols: New Methods for the Formation of Substituted Heterocycles Using Preformed and Isolated Silanolates
Author(s):Baird, John D.
Doctoral Committee Chair(s):Scott Denmark
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:A procedure for the preparation of multi-substituted indoles using the Larock indole synthesis was developed. The heteroannulation reaction can be used to prepare 2,3-disubstituted indoles in good yields. The identification of a t-butoxysilyl ether as the masked silanol further expanded the scope of this reaction.
Issue Date:2008
Type:Text
Language:English
Description:438 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2008.
URI:http://hdl.handle.net/2142/84299
Other Identifier(s):(MiAaPQ)AAI3337689
Date Available in IDEALS:2015-09-25
Date Deposited:2008


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