The Development of New Methods for the Introduction of a Vinyl Unit Using Silicon-Based Cross -Coupling Reactions

Butler, Christopher
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http://hdl.handle.net/2142/84332

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Title:The Development of New Methods for the Introduction of a Vinyl Unit Using Silicon-Based Cross -Coupling Reactions
Author(s):Butler, Christopher
Doctoral Committee Chair(s):Denmark, Scott E.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Two unsymmetrical, differentially substituted 1,2-bissilylethylene reagents were prepared and subsequently examined in sequential cross-coupling reactions. These reagents successfully react in the first coupling with aryl iodides and an electron-deficient alkenyl iodide under "fluoride-free" conditions. The second, fluoride-activated cross-coupling was explored.
Issue Date:2009
Type:Text
Language:English
Description:271 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2009.
URI:http://hdl.handle.net/2142/84332
Other Identifier(s):(MiAaPQ)AAI3362738
Date Available in IDEALS:2015-09-25
Date Deposited:2009


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