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Title:Part A. Functional Modular Phenylacetylene Units: A "Molecular Turnstile." Part B. Progress Towards an Electrochemically Active 9-Phenylcarbazole Hyperbranched Polymer
Author(s):Bedard, Thomas Craig
Doctoral Committee Chair(s):Moore, Jeffrey S.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Part B. Progress towards a new family of hyperbranched polymers based on the condensation of an AB$\sb2$ 9-phenylcarbazole monomer 169 has been described. Initial condensation reactions have provided material of greater than 100,000 mw as determined by GPC. No estimate of the degree of branching has been made. Evidence for olefinic linkages between carbazole units is provided by an observed red shifting in the absorption spectrum and chemical derivatization with bromine in carbon tetrachloride. These initial observations suggest that an in depth characterization of hyperbranched products from this family of compounds is warranted.
Issue Date:1997
Type:Text
Language:English
Description:278 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.
URI:http://hdl.handle.net/2142/84373
Other Identifier(s):(MiAaPQ)AAI9812530
Date Available in IDEALS:2015-09-25
Date Deposited:1997


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