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Title:Pentamethylcyclopentadienyl Osmium Chemistry: An Approach to Transition Metal Alkane Complexes
Author(s):Gross, Christopher L.
Doctoral Committee Chair(s):Girolami, G.S.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:Protonation of $\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me$ with $\rm HBF\sb4{\cdot}Et\sb2O$ at room temperature affords the Os$\sp{\rm IV}$ alkyl hydride complex $\lbrack\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me(H)\rbrack\lbrack BF\sb4\rbrack.$ Protonation of $\rm(C\sb5Me\sb5)Os(dmpm)Me$ at ${-}120\sp\circ$C with H2C(SO2CF3)2 in CDFC12 generates the cis methyl/hydride compound $\lbrack\rm(C\sb5Me\sb5)Os(dmpm)Me(H)\sp+\rbrack.$.
Issue Date:1997
Type:Text
Language:English
Description:261 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.
URI:http://hdl.handle.net/2142/84377
Other Identifier(s):(MiAaPQ)AAI9812601
Date Available in IDEALS:2015-09-25
Date Deposited:1997


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