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Title:Coordination Networks of Ditopic Ligands and silver(I) Salts: A Study of Factors Influencing Network Topology
Author(s):Hirsch, Keith Aaron
Doctoral Committee Chair(s):Moore, Jeffrey S.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Aggregation of 2,2$\sp\prime$-, 2,3$\sp\prime$-, and 2,4$\sp\prime$-dicyanodiphenylacetylene with silver(I) has been studied both in solution and the solid state. Solid-state topology is found to depend on the geometry of the ligand. The distribution of aggregates in solution, as determined by electrospray ionization mass spectrometry, also depends on the ligand structure. From this data, the structures of key aggregates observed in solution are proposed.
Issue Date:1997
Type:Text
Language:English
Description:426 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.
URI:http://hdl.handle.net/2142/84380
Other Identifier(s):(MiAaPQ)AAI9812619
Date Available in IDEALS:2015-09-25
Date Deposited:1997


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