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Title:Synthesis and Characterization of Mononuclear and Polynuclear Metal-Fullerene Complexes
Author(s):Hsu, Hsiu-Fu
Doctoral Committee Chair(s):Shapley, John R.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:The reaction of $\rm Ru\sb6C(CO)\sb{17}$ with C$\sb{60}$ followed by carbonyl substitution with bis(diphenylphosphino)methane gave $\rm Ru\sb6C(CO)\sb{12}(dppm)(\mu\sb3$-$\eta\sp2,\eta\sp2,\eta \sp2$-C$\sb{60}).$ A related arene-Ru$\sb6$C compound, $\rm Ru\sb6C(CO)\sb{13}\{PPh\sb2(\mu$-$\eta\sp6$-$\rm C\sb6H\sb6)\},$ was obtained by thermolysis of $\rm Ru\sb6C(CO)\sb{16}PPh\sb3,$ in which the tendency of the Ru$\sb6$C framework to form arene complexes is extend to a coordinated triphenylphosphine moiety, leading to (reversible) coordination of a phenyl ring to an adjacent ruthenium center in the cluster unit.
Issue Date:1997
Type:Text
Language:English
Description:129 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.
URI:http://hdl.handle.net/2142/84381
Other Identifier(s):(MiAaPQ)AAI9812628
Date Available in IDEALS:2015-09-25
Date Deposited:1997


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