Files in this item

FilesDescriptionFormat

application/pdf

application/pdf9812682.pdf (4MB)Restricted to U of Illinois
(no description provided)PDF

Description

Title:Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes
Author(s):Liang, Hong-Chang
Doctoral Committee Chair(s):Shapley, Patricia A.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\sb4$) ($\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ (19, R = Me; 20, R = $\rm CH\sb2SiMe\sb3)$ react with $\rm MeOSO\sb2CF\sb3$ to form $\mu\sb3$-thiolate complexes $\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-SMe)($\mu\sb3$-S) (22, R = $\rm CH\sb2SiMe\sb3$; 23, R = Me). Complex 19 reacts with ($\rm Cu(PPh\sb3)\sb2(NCMe)\sb2\rbrack\lbrack BF\sb4\rbrack$ to form ($\rm Cu(PPh\sb3)\sb2\rbrack\lbrack\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ 24.
Issue Date:1997
Type:Text
Language:English
Description:133 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.
URI:http://hdl.handle.net/2142/84384
Other Identifier(s):(MiAaPQ)AAI9812682
Date Available in IDEALS:2015-09-25
Date Deposited:1997


This item appears in the following Collection(s)

Item Statistics