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Title:Investigations of Chemiluminescence Detection Parameters for Kinetic Analysis and Capillary Separations
Author(s):Shultz, Loranelle Louise
Doctoral Committee Chair(s):Nieman, T.A.; Sweedler, J.V.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Analytical
Abstract:A post-column CL detection method for capillary electrophoresis (CE) was developed in which the capillary effluent was collected on a membrane which had been coated with bis(2,4,6-trichlorophenyl)oxalate, a CL reagent. After the CE run, the CL reaction was initiated on the membrane by applying hydrogen peroxide, a scientific CCD camera imaged the resultant CL emission, and an electropherogram was reconstructed. This post-column detection scheme decouples the separation parameters from detection and allows longer lived CL reagents to be used with fast separations.
Issue Date:1997
Type:Text
Language:English
Description:128 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.
URI:http://hdl.handle.net/2142/84392
Other Identifier(s):(MiAaPQ)AAI9812772
Date Available in IDEALS:2015-09-25
Date Deposited:1997


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