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Title:Immobilization of Ru(bpy)(3)(2+) for Electrogenerated Chemiluminescent Sensors and Application of Interdigitated Array Electrodes in Transmission Ft-Ir Spectroscopy
Author(s):Blanchard, Renee Michele
Doctoral Committee Chair(s):Nieman, T.A.; Nuzzo, Ralph G.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Analytical
Abstract:A flow cell of novel design was used to follow the changes occurring in cation-loaded Nafion films in response to variations of the humidity of a nitrogen purge gas flowing through the cell. The structural changes occurring due to the binding of water to these cation-exchanged membranes was followed across a broad range of water contents using infrared difference spectroscopy. Results demonstrate a complex role for water in mediating the polyanion-cation interactions.
Issue Date:1998
Type:Text
Language:English
Description:217 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1998.
URI:http://hdl.handle.net/2142/84419
Other Identifier(s):(MiAaPQ)AAI9912195
Date Available in IDEALS:2015-09-25
Date Deposited:1998


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