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Title:Studies in Asymmetric Catalysis. Part I. Lewis Base-Catalyzed Aldol Additions. Part II. Bis(oxazoline)palladium(ii)-Catalyzed Cyclopropanation
Author(s):Stavenger, Robert Allen
Doctoral Committee Chair(s):Denmark, Scott E.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:A variety of bis(oxazoline)palladium(II) complexes were prepared and tested in the cyclopropanation of ethyl (E)-cinnamate with diazomethane. Although an enantioselective process was never realized, effects of substitution on the ligand, catalyst loading studies, and other investigations led to a mechanistic proposal wherein partial or complete ligand dissociation occurs (depending on the ligand structure) during the course of the cyclopropanation event.
Issue Date:1999
Type:Text
Language:English
Description:399 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999.
URI:http://hdl.handle.net/2142/84438
Other Identifier(s):(MiAaPQ)AAI9921737
Date Available in IDEALS:2015-09-25
Date Deposited:1999


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