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Title:Design and Construction of Organic Solids for Second-Order Nonlinear Optics and Nanoporosity
Author(s):Zhang, Peng
Doctoral Committee Chair(s):Moore, Jeffrey S.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Polymer
Abstract:In the second part of this thesis, coordination networks based on silver(I) triflate and tetrahedral ligands functionalized with nitrile groups were found to be porous. Moreover, triflate as a coordinating counterion can be utilized as a mean to increase the predictability of the network structures. Counterion effect was further tested by the crystal structures of silver(I) 3- and 4-cyanobenzenesulfonates which are one- and two-dimensional continuous networks respectively. Finally, phenyl acetylene macrocycle functionalized with nitrile groups and longer tetrahedral ligands were synthesized and the crystallization with silver(I) salts were attempted.
Issue Date:1999
Type:Text
Language:English
Description:194 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999.
URI:http://hdl.handle.net/2142/84441
Other Identifier(s):(MiAaPQ)AAI9921762
Date Available in IDEALS:2015-09-25
Date Deposited:1999


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