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Title:The Reactivity of Tetrathioperrhenate
Author(s):Goodman, Jonathan T.
Doctoral Committee Chair(s):Rauchfuss, Thomas B.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.
Issue Date:1999
Type:Text
Language:English
Description:146 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999.
URI:http://hdl.handle.net/2142/84444
Other Identifier(s):(MiAaPQ)AAI9944864
Date Available in IDEALS:2015-09-25
Date Deposited:1999


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