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Title:Ketone -Catalyzed Epoxidation of Alkenes With Oxone and Palladium -Catalyzed Biaryl Synthesis via Silacyclobutanes
Author(s):Wu, Zhicai
Doctoral Committee Chair(s):Denmark, Scott E.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Organic
Abstract:Aryl(fluoro)silacyclobutanes and aryl(chloro)silacyclobutanes have been found to undergo cross-coupling reactions with aryl iodides. The rate of reaction and extent of homocoupling were dramatically affected by the addition of ligands for the palladium catalyst. A wide range of electronically different and structurally diverse unsymmetrical biaryls have been prepared in good to excellent yields.
Issue Date:2000
Type:Text
Language:English
Description:258 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000.
URI:http://hdl.handle.net/2142/84470
Other Identifier(s):(MiAaPQ)AAI9955682
Date Available in IDEALS:2015-09-25
Date Deposited:2000


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