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Title:Binuclear Transition Metal Derivatives of 1,2-Bis(indenyl)ethane
Author(s):Khayatpoor, Ramin
Doctoral Committee Chair(s):Shapley, John R.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:Heating Ru3(CO)12 with 1,2-bis(indenyl)ethane in xylene provided the binuclear compounds Ru2(CO)4(mu-(eta 5-C9H6)2C2H4 and [(eta5-C9H6)C2H 4(C9H7)Ru(CO)2]2. The corresponding reaction in heptane gave instead the tetranuclear cluster [Ru4H(CO) 9(mu3-eta2-eta2-eta 5-C9H6)](C2H4)(C 9H7). The structure of the rac form of Ru 2(CO)4(mu-(eta5-C9H6) 2C2H4 was determined by x-ray crystallography.
Issue Date:2000
Type:Text
Language:English
Description:159 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000.
URI:http://hdl.handle.net/2142/84484
Other Identifier(s):(MiAaPQ)AAI9990039
Date Available in IDEALS:2015-09-25
Date Deposited:2000


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