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Title:An Organometallic Approach to Iron Triazacyclononane Coordination Complexes
Author(s):Moreland, Andrew Colby
Doctoral Committee Chair(s):Rauchfuss, Thomas B.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:The active site of NiFe hydrogenase features a bis(thiolate) bridged nickel-iron site, where the iron is bound to two carbonyls and a cyanide. The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.
Issue Date:2000
Type:Text
Language:English
Description:200 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000.
URI:http://hdl.handle.net/2142/84489
Other Identifier(s):(MiAaPQ)AAI9990088
Date Available in IDEALS:2015-09-25
Date Deposited:2000


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