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Title:Synthesis and Characterization of Alkyl Tetra-, Tri-, and Triskaidecazirconates
Author(s):Pafford, Margaret Mary Elizabeth
Doctoral Committee Chair(s):Klemperer, Walter G.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:The ambient temperature hydrolysis product of tetra-n-propyl orthozirconate was identified as [Zr3O](OPrn) 10 by 13C NMR spectroscopy and elemental analysis. Ethanolysis of [Zr3O](OPrn) 10 yielded the ethoxy derivative of the trizirconate which was characterized by 13C NMR spectroscopy and elemental analysis. Reaction of the trizirconates with the parent alcohol resulted in the formation of alcohol adducts which are thought to have structures similar to that reported for {[Hf3O](OEt)10(EtOH)}2.
Issue Date:2000
Type:Text
Language:English
Description:167 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000.
URI:http://hdl.handle.net/2142/84491
Other Identifier(s):(MiAaPQ)AAI9990102
Date Available in IDEALS:2015-09-25
Date Deposited:2000


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