Files in this item

FilesDescriptionFormat

application/pdf

application/pdf9990162.pdf (7MB)Restricted to U of Illinois
(no description provided)PDF

Description

Title:Geometrical Requirements for Nucleophilic Substitution at Bivalent sulfur(II) and sulfur(VI): An Application of the Endocyclic Restriction Test
Author(s):Terrazas, Michael S.
Doctoral Committee Chair(s):Beak, Peter
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Chemistry, Inorganic
Abstract:These results suggest that substitution at both bivalent sulfur(II) and sulfur(VI) through a six-membered endocyclic ring is a high energy process. Thus, substitution is preferred through a linear transition state with respect to the incoming nucleophile and leaving group. A mechanism of this type would be most consistent with the classic SN2 pathway.
Issue Date:2000
Type:Text
Language:English
Description:148 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000.
URI:http://hdl.handle.net/2142/84501
Other Identifier(s):(MiAaPQ)AAI9990162
Date Available in IDEALS:2015-09-25
Date Deposited:2000


This item appears in the following Collection(s)

Item Statistics