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Title:Rhenium Carbido Carbonyl Cluster Complexes With Group 12 Metal Centers
Author(s):Wright, Chris Aaron
Doctoral Committee Chair(s):Shapley, John R.
Department / Program:Chemistry
Discipline:Chemistry
Degree Granting Institution:University of Illinois at Urbana-Champaign
Degree:Ph.D.
Genre:Dissertation
Subject(s):Engineering, Materials Science
Abstract:Exploration of mercury capped rhenium carbido carbonyl clusters as potential labeling agents was initiated. The reaction of [PPh4]2[Re 7C(CO)21HgCl] with L-cysteine in aqueous acetone formed the complex [PPh4]2[Re7C(CO)21HgSCH 2CH(NH3)CO2]. In order to explore further reactions in aqueous solution, work was carried out with [Na]2[Re7C(CO) 21HgCl]. Preliminary work indicates that this complex has potential as an electron dense, easily detectable label for sulfhydryl sites in proteins.
Issue Date:2000
Type:Text
Language:English
Description:178 p.
Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000.
URI:http://hdl.handle.net/2142/84503
Other Identifier(s):(MiAaPQ)AAI9990193
Date Available in IDEALS:2015-09-25
Date Deposited:2000


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