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Title:Microwave measurements of cyclopropanecarboxylic acid and its doubly hydrogen bonded dimer with formic acid
Author(s):Pejlovas, Aaron M.
Contributor(s):Kukolich, Stephen G.; Lin, Wei
Subject(s):Spectroscopy of Large Amplitude Motions
Abstract:\begin{wrapfigure}{r}{0pt} \includegraphics[scale=0.3]{cis3.eps} \end{wrapfigure} The microwave spectra were measured for cyclopropanecarboxylic acid (CPCA), an excited state conformer of CPCA and a doubly hydrogen bonded dimer formed with formic acid (FA) using a pulsed-beam Fourier transform microwave spectrometer. The rotational constants were determined from the spectra and were used to obtain a best fit gas phase structure of both CPCA and CPCA-FA using a nonlinear least squares fitting program. We obtained the C-C bond lengths in the cyclopropane ring for CPCA and the hydrogen bond distances for the CPCA-FA dimer. For CPCA-FA, there was no evidence of a concerted double proton tunneling motion as singlet b-type transitions were observed. The absence of the tunneling motion is most likely due to the asymmetry of the dimer. The excited stated conformer of the CPCA-FA dimer was also searched for, but was also not observed.
Issue Date:2016-06-21
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper / Presentation
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2017-01-26

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