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Title:Electronic spectra of tris(2,2'-bipyridine)-metal complex ions in gas phase
Author(s):Xu, Shuang
Contributor(s):Weber, J. Mathias; Smith, James E. T.
Subject(s):Spectroscopy in Traps
Abstract:Tris(bpy)-metal complexes (bpy = 2,2'-bipyridine) and their derivatives are important systems in metal-organic chemistry. While tris(bpy)-ruthenium, \chem{Ru(bpy)_{3}^{2+}}, has been extensively studied, less attention has been paid to analogous complexes involving first row transition metals. Here we report the electronic spectra of a series of dicationic tris(bpy) chelates with different transition metals, measured by photodisscociation spectroscopy of cryogenically prepared ions. We focus our attention on the $\pi$-$\pi$ transitions in the UV region of the spectrum.
Issue Date:2016-06-21
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper/Presentation
Type:Text
Language:En
URI:http://hdl.handle.net/2142/91129
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2016-08-22


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