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Title:Structures and solvation effects of [Fe(CO2)n]− cluster anions
Author(s):Thompson, Michael C.
Contributor(s):Weber, J. Mathias
Subject(s):Clusters/Complexes
Abstract:We present infrared photodissociation spectra of [Fe(\chem{CO_2})$_{n}$]$^{-}$ ($n=3-7$) cluster anions. We use density functional theory to compare calculated vibrational frequencies to our experimental spectra to determine plausible structures for the molecular charge carriers. The spectra display similar characteristics to those of other complexes of first-row transition metals with \chem{CO_2} ligands, and show signatures of several structural motifs.
Issue Date:2016-06-22
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper/Presentation
Type:Text
Language:En
URI:http://hdl.handle.net/2142/91131
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2016-08-22


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