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Title:Determination of the preferred structure, dynamics, and planarity of substituted anhydrides by cp-ftmw
Author(s):Bird, Ryan G.
Contributor(s):Pratt, David; Bailey, Josiah R.; McMahon, Timothy J.
Subject(s):Structure determination
Abstract:The planarity of five-membered rings is derived from a competition between ring-angle strain and stability of the torsional angles. The planar form maximizes the already stressed, smaller-than-normal, C-C bond angles, while puckering reduces the unfavorable eclipsed interactions. The structure, dynamics, and planarity of three anhydrides, succinic, methylsuccinic, and methylene (itaconic) anhydride, were studied and compared using chirped-pulse Fourier transform microwave spectroscopy.
Issue Date:2016-06-20
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper/Presentation
Type:Text
Language:En
URI:http://hdl.handle.net/2142/91297
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2016-08-22


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