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## Description

 Title: The pure rotational spectra of FCPtF and FptI Author(s): Walker, Nick Contributor(s): Legon, Anthony; Bittner, Dror M. Subject(s): Metal containing Abstract: Transitions measured by a chirped pulse Fourier transform microwave spectrometer in the frequency range 6.5-18.5 GHz have been fitted and tentatively assigned to the linear molecules FCPtF and FPtI, each in a $^1\Sigma$ electronic state. Laser ablation was used to introduce Pt into the gas phase from a metal rod with natural isotopic abundance. \chem{CF_3I} was used as a source of C, F and I atoms. The products of reactions between the chemical precursors were cooled to a rotational temperature approaching 2K through supersonic expansion of the gaseous sample. Different isotopologues of Pt were observed. The spectra of other palladium and platinum containing complexes obtained in a similar way will be presented. Issue Date: 2016-06-23 Publisher: International Symposium on Molecular Spectroscopy Genre: Conference Paper/Presentation Type: Text Language: En URI: http://hdl.handle.net/2142/91341 Rights Information: Copyright 2016 by the authors Date Available in IDEALS: 2017-01-26
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