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Title:The pure rotational spectra of FCPtF and FptI
Author(s):Walker, Nick
Contributor(s):Legon, Anthony; Bittner, Dror M.
Subject(s):Metal containing
Abstract:Transitions measured by a chirped pulse Fourier transform microwave spectrometer in the frequency range 6.5-18.5 GHz have been fitted and tentatively assigned to the linear molecules FCPtF and FPtI, each in a $^1\Sigma$ electronic state. Laser ablation was used to introduce Pt into the gas phase from a metal rod with natural isotopic abundance. \chem{CF_3I} was used as a source of C, F and I atoms. The products of reactions between the chemical precursors were cooled to a rotational temperature approaching 2K through supersonic expansion of the gaseous sample. Different isotopologues of Pt were observed. The spectra of other palladium and platinum containing complexes obtained in a similar way will be presented.
Issue Date:2016-06-23
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper / Presentation
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2017-01-26

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