## Files in this item

FilesDescriptionFormat

application/vnd.openxmlformats-officedocument.presentationml.presentation

738771.pptx (10MB)
PresentationMicrosoft PowerPoint 2007

application/pdf

2013.pdf (16kB)
AbstractPDF

## Description

 Title: Modeling photodetachment from HO2− using the pd case of the generalized mixed character molecular orbital model Author(s): Blackstone, Christopher C Contributor(s): Sanov, Andrei Subject(s): Spectroscopy in Atmospheric Chemistry Abstract: Using the generalized model for photodetachment of electrons from mixed-character molecular orbitals, we gain insight into the nature of the HOMO of HO$_{2}$$^{-} by treating it as a coherent superpostion of one p- and one d-type atomic orbital. Fitting the pd model function to the ab initio calculated HOMO of HO_{2}$$^{-}$ yields a fractional d-character, $\gamma$$_{p}$, of 0.979. The modeled curve of the anisotropy parameter, $\beta$, as a function of electron kinetic energy for a pd-type mixed character orbital is matched to the experimental data. Issue Date: 2016-06-21 Publisher: International Symposium on Molecular Spectroscopy Genre: Conference Paper/Presentation Type: Text Language: En URI: http://hdl.handle.net/2142/91415 Rights Information: Copyright 2016 by the authors Date Available in IDEALS: 2017-01-26
﻿