Files in this item

FilesDescriptionFormat

application/pdf

application/pdf2092.pdf (13kB)
AbstractPDF

Description

Title:Isomer specific microwave spectrum of (E)- and (Z)- phenylvinylnitrile. Implementing a new multi-resonant spectral analysis tool.
Author(s):Hernandez-Castillo, Alicia O.
Contributor(s):Zwier, Timothy S.; Abeysekera, Chamara; Hays, Brian M.
Subject(s):Spectroscopy in Atmospheric Chemistry
Abstract:There are many circumstances in modern microwave spectroscopy where the observed spectra contain contributions from many distinct sub-populations, creating a complicated spectrum with interleaved transitions due to its components making spectral assignment challenging. A new method, exploiting multi resonance effects with broadband CP-FTMW was developed and implemented to differentiate the structural isomers: (E)- and (Z)-phenylvinylnitrile. This method will output an exclusive set of isomer-specific transitions reducing the spectral assignment time. Details of the method implementation and structural analysis of the two-isomer mixture will be discussed. The application of the method to other circumstances where selective modulation of the transitions due to a single set of connected transitions is vital for complex spectral assignment, will also be considered.
Issue Date:2016-06-21
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper/Presentation
Type:Text
Language:En
URI:http://hdl.handle.net/2142/91471
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2016-08-22


This item appears in the following Collection(s)

Item Statistics