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Title:CP-FTMW spectrum of bromoperfluoroacetone
Author(s):Marshall, Frank E.
Contributor(s):Grubbs II, G. S.; Gillcrist, David Joseph; Persinger, Thomas D.; Moon, Nicole
Subject(s):(Hyper)fine structure, tunneling
Abstract:The microwave spectrum of the molecule bromoperfluoroacetone has been measured on a CP-FTMW spectrometer in the 6-18. The spectra is dense with approximately one transition every 5 MHz on average. Rotational constants, centrifugal distortion parameters, and nuclear quadrupole coupling constants will be discussed. Comparisons to the previously studied halogen analogues perfluoroacetone\footnote{J.-U. Grabow, N. Heineking, and W. Stahl, \textit{Z. Naturforsch.} \textbf{46a} (1991) 229.} and chloroperfluoroacetone\footnote{G. Kadiwar, C. T. Dewberry, G. S. Grubbs II and S. A. Cooke, Talk \textbf{RH11}, 65$^{\mathrm{th}}$ International Symposium on Molecular Spectroscopy (2010).} along with a family of previously studied halogenated acetone species will be discussed.
Issue Date:2016-06-22
Publisher:International Symposium on Molecular Spectroscopy
Genre:Conference Paper / Presentation
Rights Information:Copyright 2016 by the authors
Date Available in IDEALS:2017-01-26

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