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Title:CORE ION STRUCTURES AND SOLVATION EFFECTS IN GAS PHASE [Sn(CO2)n]− CLUSTERS
Author(s):Thompson, Michael C
Contributor(s):Weber, J. Mathias
Subject(s):Clusters/Complexes
Abstract:We report infrared photodissociation spectra of $textrm {[Sn(CO}_{2})_{n}]$ ($n$=2-6) clusters. We explore core ion geometries through quantum chemical calculations and assign our experimental spectra through comparison with calculated vibrational frequencies. We discuss our results in the context of heterogeneous catalytic reduction of CO$_{2}$, and compare our results with previous work on other post-transition metal species.
Issue Date:6/23/2017
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/96796
DOI:10.15278/isms.2017.FD04
Date Available in IDEALS:2017-07-27


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