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Title:TAKING THE NEXT STEP WITH HALOGENATED OLEFINS: MICROWAVE SPECTROSCOPY AND MOLECULAR STRUCTURES OF TETRAFLUORO- AND CHLORO-TRIFLUORO PROPENES AND THEIR COMPLEXES WITH THE ARGON ATOM
Author(s):Marshall, Mark D.
Contributor(s):Dao, Alina K; Randy-Cofie, Allison M; Hoque, Laboni; Tracy, Megan E; Wronkovich, Miles A.; Leung, Helen O.
Subject(s):Structure determination
Abstract:The determination of the structures of heterodimers of haloethylenes with protic acids has provided a wealth of information and a few surprises concerning intermolecular forces and the sometimes cooperative and sometimes competing effects of electrostatic, steric, and dispersion forces. In seeking to apply this knowledge to larger systems with a wider variety of possible interactions and binding sites, we extend the carbon chain by one atom via the addition of a trifluoromethyl moeity. As a first step the microwave rotational spectra of the halopropene monomers, 2,3,3,3-tetrafluoropropene, 2-chloro-3,3,3-trifluoropropene, ({it E})-1-chloro-3,3,3-trifluoropropene, and ({it Z})-1-chloro-3,3,3-trifluoropropene, and their complexes with the argon atom are obtained and analyzed to obtain molecular structures.
Issue Date:6/20/2017
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/96817
DOI:10.15278/isms.2017.TC07
Date Available in IDEALS:2017-07-27


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