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Title:THE ν3 FUNDAMENTAL VIBRATIONAL BAND OF SCCCS REVISITED
Author(s):Thorwirth, Sven
Contributor(s):Dudek, John B; Salomon, Thomas
Subject(s):Clusters/Complexes
Abstract:The $nu_3$ fundamental vibrational band of carbon subsulfide, SCCCS, first studied by Holland_x000d_ and collaboratorsfootnote{F. Holland, M. Winnewisser, C. Jarman, H. W. Kroto, and K. M. T. Yamada 1988, textit{J. Mol. Spectrosc.} 130, 344}$^,$footnote{F. Holland and M. Winnewisser 1991, textit{J. Mol. Spectrosc.} 147, 496} has been reinvestigated using a combination of laser ablation production, free-jet expansion and quantum cascade laser spectroscopy. In addition to the fundamental band (located at 2100,cm$^{-1}$) and associated hot bands originating from the lowest bending mode $nu_7$, the hot bands from the two energetically higher-lying bending modes $nu_5$ and $nu_6$ have been observed for the first time as has the S$^{13}$CCCS isotopic species.
Issue Date:6/23/2017
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/96828
DOI:10.15278/isms.2017.FD03
Date Available in IDEALS:2017-07-27


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