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Title:THE COMPLETE HEAVY-ATOM STRUCTURE OF A CP-FTMW CHIRAL TAG PRECURSOR, VERBENONE
Author(s):Marshall, Frank E
Contributor(s):Grubbs II, G. S.; Pate, Brooks; Sedo, Galen; West, Channing
Subject(s):Mini-symposium: Chirality-Sensitive Spectroscopy
Abstract:The microwave spectrum of the chiral molecule verbenone has been recorded from 2-18 GHz using two CP-FTMW spectrometers. 2-8 GHz data has been acquired on a 2-8 GHz CP-FTMW located at the University of Virginia and 8-18 data has been acquired on a 6-18 GHz spectrometer located at Missouri S&T. From the experiments the authors were able to assign and fit isotopologues corresponding to each heavy atom position (either $^{13}$C or $^{18}$O), providing for the heavy-atom structure. Previous studies by Evans and coworkers have been added to these measurements in a global fit of the parent species.footnote{C. J. Evans, S. M. Allpress, P. D. Godfrey, D. McNaughton, textit{67th International Symposium on Molecular Spectroscopy}, 2012, textbf{RH13}}$^{,}$footnote{S. M. Allpress, textit{Spectroscopic and Computational Chemistry Studies on Terpene Related Compounds}, University of Leicester, 2015, Chapter 6: Microwave Spectroscopy of Verbenone} The measurement and assignment of these transitions provide preliminary information needed for enatiomeric excess experiments using CP-FTMW van der Waals-type chiral tagging processes already being performed at UVa. Details of the experiment, fits, and structure will be discussed.
Issue Date:6/22/2017
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/96882
DOI:10.15278/isms.2017.RG12
Date Available in IDEALS:2017-07-27


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