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Title:O(3 P) DOPED HELIUM DROPLETS
Author(s):Brice, Joseph T.
Contributor(s):Douberly, Gary E.
Subject(s):Radicals
Abstract:Atomic oxygen $(^3 P)$ is generated via thermolysis in a commerical thermal gas cracker (Mantis Ltd. MGC-75). Complexes with HCN were investigated to qualitatively assess the doping efficiency of O$(^3 P)$ into a helium droplet. Theoretical calculations of a linear O$,cdot!cdot!cdot,$HCN $(^3 Sigma)$ complex at the CCSD(T)/aug-cc-pVTZ level are consistent with the rotational constants extracted from the rotational substructure in the experimental spectra, and with dipole moments approximated from Stark spectra. The thermal source will be used to study reactions between O$(^3 P)$ and hydrocarbons in helium droplets, and preliminary data on this topic will be presented.
Issue Date:6/22/2017
Publisher:International Symposium on Molecular Spectroscopy
Citation Info:APS
Genre:CONFERENCE PAPER/PRESENTATION
Type:Text
Language:English
URI:http://hdl.handle.net/2142/96974
DOI:10.15278/isms.2017.RJ02
Date Available in IDEALS:2017-07-27


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