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Pirkle, William H. Lee, Wonjae 2011-05-07T13:33:23Z 2011-05-07T13:33:23Z 10000-01-01 1994 From mechanistic considerations, the development of conformationally rigid chiral stationary phases (CSPs) has been a goal. Several conformationally rigid CSPs derived from $\alpha$-amino-lactams have been prepared and their abilities to separate the enantiomers of a variety of analytes have been evaluated. $\pi$-Acidic $\alpha$-amino-$\beta$-lactam-derived CSPs have been designed specifically for the enantioseparation of underivatized $\beta$-blockers. A systematic study of chromatographic structure-activity relationships for the resolution of $\pi$-acidic dinitrobenzoyl (DNB) amino acid derivatives on several DNB $\pi$-acidic CSPs has been carried out. Related to these studies, X-ray crystallographic structure determinations have been pursued in a quest for the origins of chiral-self recognition. Made available in DSpace on 2011-05-07T13:33:23Z (GMT). No. of bitstreams: 2 license.txt: 4922 bytes, checksum: 910b249b4beec47e7ab768910c8f966f (MD5) 9512455.pdf: 5046572 bytes, checksum: 519b9c0ee70d3aec2d845f70ab60842d (MD5) Previous issue date: 1994 Item marked as restricted to the 'UIUC Users [automated]' Group (id=2) by Howard Ding (hding2@illinois.edu) on 2011-05-07T14:56:14Z Item is restricted indefinitely. Restriction data tranferred 2014-07-01T11:26:16-05:00 Original Data Group with Access UIUC Users [automated] Release Date: none Reason: ETDs are only available to UIUC Users without author permission ETDs are only available to UIUC Users without author permission U of I Only AAI9512455 (UMI)AAI9512455 http://hdl.handle.net/2142/22235 eng Copyright 1994 Lee, Wonjae Chemistry, Organic Investigations of chiral recognition of conformationally rigid chiral stationary phases text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.