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Porter, Judith Elizabeth 2014-12-15T23:18:30Z 2014-12-15T23:18:30Z 10000-01-01 1985 1985 The three malonyl peroxides 4-methyl-4-phenyl-1,2-dioxolane-3,5-dione (3), 4-diphenylmethyl-4-methyl-1,2-dioxolane-3,5-dione (4), and 4-methyl-4-(1-propenyl)-1,2-dioxolane-3,5-dione (5) are prepared by the methanesulfonic acid catalyzed reaction of hydrogen peroxide with the parent malonic acids. Weak chemiluminescence is observed from all three peroxides when they are thermolyzed in the presence of an aromatic fluorescer. The CIEEL mechanism is applied to explain the production of the light in each system. The production of the light in each case is very inefficient. The attempted synthesis of a fourth malonyl peroxide, 4-methyl-4-(trans-(beta)-styryl)-1,2-dioxolane-3,5-dione (6), is also presented. Made available in DSpace on 2014-12-15T23:18:30Z (GMT). No. of bitstreams: 1 8521861.pdf: 4186878 bytes, checksum: d3b19e9c5ef356ff9801458232f03f55 (MD5) Previous issue date: 1985 Embargo set by: Seth Robbins for item 70469 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 149 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1985. http://hdl.handle.net/2142/70303 (UMI)AAI8521861 Chemistry, Organic Synthesis and Chemiluminescent Investigation of Malonyl Peroxides text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.