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Adams, James B. Siegel, Donald Jason 2015-09-25T20:02:38Z 2015-09-25T20:02:38Z 10000-01-01 2001 2001 Although we find significant differences in both the interfacial bonding and the inherent electronic structures of the bulk ceramics, our calculations reveal a trend in Wad with respect to the summed surface energies of the interfaced materials (sigmaAl + sigmaceramic). Specifically, we find that surfaces having larger sigma's adhere at interfaces more strongly than those with small sigma's. We argue that this behavior is consistent with the intuitive notion of the surface energy being a measure of surface reactivity, and hence it could be used as a guide in the design of interfacial properties. Made available in DSpace on 2015-09-25T20:02:38Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3023197.pdf: 7212861 bytes, checksum: 010041371894122497e4456733bdb503 (MD5) Previous issue date: 2001 Embargo set by: Seth Robbins for item 81754 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 128 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001. http://hdl.handle.net/2142/80472 (MiAaPQ)AAI3023197 eng Engineering, Materials Science First-Principles Study of Metal -Ceramic Interfaces text Physics Physics University of Illinois at Urbana-Champaign Dissertation Ph.D.