2026-09-20T01:22:45Z https://www.ideals.illinois.edu/oai-pmh

oai:www.ideals.illinois.edu:2142/82407 2023-07-11 col_2142_5131 col_2142_11615 com_2142_5130 com_2142_9130 com_2142_8903

Zhi Li He, Guangwen 2015-09-25T20:43:37Z 2015-09-25T20:43:37Z 10000-01-01 2007 2007 The goals of this research are: (i) to study the effects of the rate of supersaturation on crystallization kinetics and polymorph selectivity; and (ii) to develop a generalized phase diagram from first principles and verify its applicability to a wide range of molecular solutions. This thesis investigates how the rate of supersaturation affects macroscopic phase transitions and final crystal properties and how the microscopic particle interactions influence both the equilibrium solution phase behavior such as solubility boundary and the nonequilibrium phase transitions such as liquid-liquid phase separation and gel formation. Made available in DSpace on 2015-09-25T20:43:37Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3314788.pdf: 3625713 bytes, checksum: bb13f463846dc7a25ef8b3b83af9a451 (MD5) Previous issue date: 2007 Embargo set by: Seth Robbins for item 83688 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 142 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007. http://hdl.handle.net/2142/82407 (MiAaPQ)AAI3314788 eng Chemistry, Physical Crystallization Kinetics and Phase Behavior of Molecular Solutions text Chemical Engineering Chemical Engineering University of Illinois at Urbana-Champaign Dissertation Ph.D.