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oai:www.ideals.illinois.edu:2142/82439 2023-07-11 col_2142_5131 col_2142_11615 com_2142_5130 com_2142_9130 com_2142_8903

Masel, Richard I. Cong, Yu 2015-09-25T20:44:04Z 2015-09-25T20:44:04Z 10000-01-01 1997 1997 To study the surface work function effect on the surface reaction mechanism, ethanol and fluorinated ethanol decomposition have also been studied on clean and oxygen precovered (2 x 1)Pt(110) surface. The reaction mechanism is very similar on clean (2 x 1)Pt(110) as on Pt(331), except the ethanol C-C bond scission is suppressed on Pt(110). On oxygen precovered (2 x 1)Pt(110) surface the C-C bond scission occurred at higher temperature than on Pt(331), but from the slope of the Hammett plot, it is shown that on (2 x 1)Pt(110) the hydrogen has less charge than on Pt(331), which can be expected from the higher surface work function of the Pt(110) surface. Made available in DSpace on 2015-09-25T20:44:04Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9812565.pdf: 4487334 bytes, checksum: 436dfd985e80b4512ad30afb9da5b864 (MD5) Previous issue date: 1997 Embargo set by: Seth Robbins for item 83720 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 198 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997. http://hdl.handle.net/2142/82439 (MiAaPQ)AAI9812565 eng Chemistry, Physical Ethanol and Fluorinated Ethanol Decomposition on Single Crystal Platinum Surfaces: Structure Sensitivity and Electronic Effects text Chemical Engineering Chemical Engineering University of Illinois at Urbana-Champaign Dissertation Ph.D.