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Masel, Richard I. Ford, Laura Page 2015-09-25T20:44:14Z 2015-09-25T20:44:14Z 10000-01-01 1999 1999 The reactions of 1,1,1,5,5,5-hexafluoro-2,4-pentanedione on O/Pt(110) have been studied with temperature-programmed desorption. Unlike hexafluoropentanedione on oxygen-precovered nickel and copper, hexafluoropentanedione does not etch oxygen-precovered platinum. Hexafluoropentanedione decomposes below 350 K, yielding acetaldehyde, trifluoroacetone, and carbon that remains on the surface. An unidentified compound desorbs from the surface as well. The decomposition of hexafluoropentanedione on O/Pt(110) means that it will not be a good etchant for platinum. Made available in DSpace on 2015-09-25T20:44:14Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9944853.pdf: 5260253 bytes, checksum: ac906e7e1cc9c16b568fd9c7de321835 (MD5) Previous issue date: 1999 Embargo set by: Seth Robbins for item 83748 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 139 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999. http://hdl.handle.net/2142/82467 (MiAaPQ)AAI9944853 eng Engineering, Materials Science Challenging Theories in Surface Science: Models of Active Sites and Carbon Monoxide Surface Binding text Chemical Engineering Chemical Engineering University of Illinois at Urbana-Champaign Dissertation Ph.D.