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Zimmerman, Steven C. Wendland, Michael Scott 2015-09-25T22:12:28Z 2015-09-25T22:12:28Z 10000-01-01 2001 2001 Analogous to molecular imprinted polymers, cored dendrimers were imprinted by synthesizing the structure in the presence of a template (core unit). Porphyrins were found to be useful target compounds for which to imprint cored dendrimers. The porphyrins were used as spectrophotometric probes to determine the selectivity of the cored dendrimer. Binding studies with various functionalized porphyrins and the cored dendrimer were monitored by UV/Vis spectroscopy. The results showed that these cored dendrimers were selective for porphyrins complementary in both shape and functionality to the binding site created in their interior. The binding behavior of these cored dendrimers was found to be sensitive to the conditions used for the cross-linking reaction. Made available in DSpace on 2015-09-25T22:12:28Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3017250.pdf: 8745434 bytes, checksum: b0607bfb866cfb09cc839941bf1ffa19 (MD5) Previous issue date: 2001 Embargo set by: Seth Robbins for item 85312 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 188 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2001. http://hdl.handle.net/2142/84031 (MiAaPQ)AAI3017250 eng Chemistry, Organic Cored Dendrimers: Synthesis and Applications text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.