2026-09-23T00:24:16Z https://www.ideals.illinois.edu/oai-pmh

oai:www.ideals.illinois.edu:2142/84079 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

2002 Mechanistic elucidation of an oxygen transfer reaction was sought by the application of the endocyclic restriction test toward an aldehyde-mediated epoxidation of olefins by molecular oxygen. The differentiation between alternate oxygen transfer reagents is provided by stereochemical studies, and well as by results from the endocyclic restriction test. Support for a radical chain mechanism that relies on an acylperoxy radical as the active oxidant is provided. Subsequent decarboxylation and epoxide ring-opening are proposed to rationalize the furan product obtained from the reaction. Beak, Peter Jarboe, Stephen Gary 2015-09-25T22:12:45Z 2015-09-25T22:12:45Z 10000-01-01 2002 Made available in DSpace on 2015-09-25T22:12:45Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3070337.pdf: 4521306 bytes, checksum: 97ec0d6bf45065203ffc609a58e2a9d7 (MD5) Previous issue date: 2002 Embargo set by: Seth Robbins for item 85360 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 100 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2002. http://hdl.handle.net/2142/84079 (MiAaPQ)AAI3070337 eng Chemistry, Organic The Endocyclic Restriction Test: Mechanistic Investigations of Sulfur and Oxygen Transfer Reactions text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.