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Beak, Peter Kim, Dwight D. 2015-09-25T22:13:00Z 2015-09-25T22:13:00Z 10000-01-01 2003 2003 Modification of the allyl amine with selected substituents at the beta and gamma-positions allowed for an examination of yields, product distributions, enantioenrichments, mechanistic understanding and synthetic applications. With an extended allyl amine, enantioenriched diene products were obtained which participated in highly selective Diels-Alder cyclizations. Methyl substitution at the beta-position gave a substrate suitable for mechanistic studies. The addition of a heteroaromatic ring on the allyl backbone provided a substrate that behaved very similarly to the cinnamyl analogue. The robust nature of the furan ring was observed as a variety of conditions needed for enecarbamate transformations did not affect the ring stability. Made available in DSpace on 2015-09-25T22:13:00Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3101882.pdf: 8474930 bytes, checksum: 79331993d8b4ec1e120dc27ea06b07dc (MD5) Previous issue date: 2003 Embargo set by: Seth Robbins for item 85397 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 177 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003. http://hdl.handle.net/2142/84116 (MiAaPQ)AAI3101882 eng Chemistry, Organic Asymmetric Lithiation-Substitution Sequences of Functionalized Allylic and Benzylic Amines Mediated by (-)-Sparteine text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.