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oai:www.ideals.illinois.edu:2142/84128 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

Gin, David Y. Nguyen, Hien Minh 2015-09-25T22:13:04Z 2015-09-25T22:13:04Z 10000-01-01 2003 2003 Our efforts for the development of novel strategies for the total synthesis of auriside A are present in the third part of the dissertation. The hemiacetal disaccharide portion of auriside A is successfully synthesized. The convergent synthesis of the auriside aglycon component is accomplished in 17 linear steps using the Mukaiyama aldol reaction, the intramolecular Mitsunobu macrolactonization, and the Julia olefination for the installation of the C(5)-stereogenic center, the 14-membered macrolactone, and the conjugated bromodiene moiety, respectively. Made available in DSpace on 2015-09-25T22:13:04Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3111623.pdf: 11522056 bytes, checksum: a0b813652d8c331c3da85c7e6f991167 (MD5) Previous issue date: 2003 Embargo set by: Seth Robbins for item 85409 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 301 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003. http://hdl.handle.net/2142/84128 (MiAaPQ)AAI3111623 eng Chemistry, Organic I. Chemoselective Dehydrative Glycosylation With Application Toward Oligosaccharide Synthesis. II. Sulfide-Mediated Direct Glycosylation of C(1)-Hydroxyl Glycosyl Donors. III. Studies Toward the Total Synthesis of Auriside A text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.