2026-09-21T02:47:32Z https://www.ideals.illinois.edu/oai-pmh

oai:www.ideals.illinois.edu:2142/84130 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

Kenneth S. Suslick Smithenry, Dennis William 2015-09-25T22:13:04Z 2015-09-25T22:13:04Z 10000-01-01 2003 2003 The manganese porphyrin framework, PIZA-5, has been shown to catalyze the hydroxylation of cycloalkanes under liquid-solid conditions, using iodosylbenzene as oxidant. This framework is novel as the catalysis occurs in its pores. No other porphyrin framework solids where catalysis occurs in the pores have been reported in the literature to date, even though this is the most often cited application for the research. Another impressive feature of PIZA-5 is that it hydroxylates cycloalkanes in a size- and polarity-selective manner. The cobalt porphyrin framework, PIZA-6, was not found to be an effective catalyst under liquid-solid conditions, using iodosylbenzene as oxidant. Made available in DSpace on 2015-09-25T22:13:04Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3111641.pdf: 5818157 bytes, checksum: 34c497f1e7ba1aebd79d9fced80e77a4 (MD5) Previous issue date: 2003 Embargo set by: Seth Robbins for item 85411 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 140 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003. http://hdl.handle.net/2142/84130 (MiAaPQ)AAI3111641 eng Chemistry, Inorganic Robust Microporous Metalloporphyrin Framework Solids text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.