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2004 Shapley, Patricia A. Shapley, John R. Lutz, Christopher Michael 2015-09-25T22:13:07Z 2015-09-25T22:13:07Z 10000-01-01 2004 Reaction of [N(n-Bu)4][M(N)Me4] with Me3SiOSO2CF3 yielded the neutral complexes Os(NSiMe3)Me4 and Ru(NSiMe3)Me4. These complexes reacted with water to generate Me3SiOH, CH 4, (Me3Si)2O and insoluble metal-containing species. Both reacted with carbon monoxide to form acetone derived from the alkyl ligands. Neither complex reacted with styrene. Trialkyl- and triarylphosphines trapped decomposition products and formed new compounds including Os(N)(PPh3 )Me3 and Os(N)(PMe3)Me3. Mixtures of Os(NSiMe3)Me4, styrene, and N-tosyliminophenyliodinane produced some nitrogen transfer product, cyclo-(tosyl)NCH 2CHPh. Made available in DSpace on 2015-09-25T22:13:07Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3130974.pdf: 6077787 bytes, checksum: f0de289dea354baa716cbc7235a2aa0e (MD5) Previous issue date: 2004 Embargo set by: Seth Robbins for item 85417 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 142 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2004. http://hdl.handle.net/2142/84136 (MiAaPQ)AAI3130974 eng Chemistry, Inorganic Synthesis and Reactivity of ruthenium(VI) and osmium(VI) Nitrido and Imido Complexes text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.