2026-09-21T11:06:03Z https://www.ideals.illinois.edu/oai-pmh

oai:www.ideals.illinois.edu:2142/84155 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

Gewirth, Andrew A. Xiao, Li 2015-09-25T22:13:14Z 2015-09-25T22:13:14Z 10000-01-01 2004 2004 Finally, thiocyanate (SCN) adsorption on Au electrode is examined. Both the calculations and the spectroscopy show that three different geometries are adopted by SCN in the potential region studied (0.0 V ≤ E ≤ 1.2 V vs. NHE). At low potential both N-bound and S-bound forms are found, at intermediate potentials around Epzc the S-bound form dominates, and at high potentials SCN associates with the surface via a bridging geometry. The different Stark slopes observed for the C-N stretch in the end-on and bridging forms are attributed to the lowest unoccupied molecular orbital (LUMO). Made available in DSpace on 2015-09-25T22:13:14Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3153362.pdf: 20396396 bytes, checksum: 17efff5b7b1bc9b4585f58fef86ad35a (MD5) Previous issue date: 2004 Embargo set by: Seth Robbins for item 85436 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 259 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2004. http://hdl.handle.net/2142/84155 (MiAaPQ)AAI3153362 eng Chemistry, Analytical Dioxygen Electroreduction on Electrode Surfaces text Ph.D. Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation