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Rauchfuss, Thomas B. Kuhlman, Matthew Lee 2015-09-25T22:13:17Z 2015-09-25T22:13:17Z 10000-01-01 2004 2004 The metal sulfide cluster, [(cymene)2Ru3S 2(NCMe)3]2+, reacts with various equivalents of sulfide to give rise to cluster-of-clusters i.e. [(cymene)4Ru 5S4]2+ and [(cymene)6Ru9S 8]2+. The new valence isomer of the [(cymene)4Ru 4S3]2+ was characterized and shown to convert to the black Roussin motif. Finally, this work also demonstrates the potential utility of Ru-S clusters as catalysts for hydrogen production. Made available in DSpace on 2015-09-25T22:13:17Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3160908.pdf: 13209208 bytes, checksum: f01f0ecec09de0a95f1579aaac8588cb (MD5) Previous issue date: 2004 Embargo set by: Seth Robbins for item 85449 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 222 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2004. http://hdl.handle.net/2142/84168 (MiAaPQ)AAI3160908 eng Chemistry, Inorganic The Design of Cyanometallate Cages for Alkali Ion Separation text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.