2026-09-23T06:30:02Z https://www.ideals.illinois.edu/oai-pmh

oai:www.ideals.illinois.edu:2142/84191 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

2005 The scope and limitations of [PPh4][Ru(N)Me2(mu-O) 2Pd((-)-sparteine)] as a catalytic aerobic oxidant of organic alcohols is explored. The complex [PPh4][Ru(N)Me2(mu2 -O)2Pd((-)-sparteine)] oxidizes aryl and allyl alcohols to their corresponding aldehydes. The complex also catalytically rearranges allylic alcohols to their corresponding unsaturated aldehydes. The mechanism of oxidation for [PPh4][Ru(N)Me(mu2-O)2Pd((-)-sparteine)] closely mirrors that of the previously described heterobimetallic complex [N(n-Bu4)][Os(N)(CH2SiCH3)2(mu 2-O)2CrO2]. It is first order in complex and first order in benzyl alcohol. Made available in DSpace on 2015-09-25T22:13:24Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3199052.pdf: 5071701 bytes, checksum: ab72eefbfbb3e5f6781009f4948a9f7e (MD5) Previous issue date: 2005 Shapley, Patricia A. Kuiper, Jesse Lee 2015-09-25T22:13:24Z 2015-09-25T22:13:24Z 10000-01-01 2005 Embargo set by: Seth Robbins for item 85472 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 205 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2005. http://hdl.handle.net/2142/84191 (MiAaPQ)AAI3199052 eng Chemistry, Organic Synthesis of Heterometallic nitridoruthenium(VI) Complexes With Nickel, Palladium, or Platinum: New Catalysts for the Aerobic Oxidation of Alcohols text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.